PSRK Prediction of Critical Points in Binary Mixtures Containing Alkanes or Cycloalkanes.
نویسندگان
چکیده
منابع مشابه
Conformations of Alkanes and Cycloalkanes
Hydrogen peroxide is formed in the cells of plants and animals but is toxic to them. Consequently, living systems have developed mechanisms to rid themselves of hydrogen peroxide, usually by enzyme-catalyzed reduction to water. An understanding of how reactions take place, be they reactions in living systems or reactions in test tubes, begins with a thorough knowledge of the structure of the re...
متن کامل2: Alkanes and Cycloalkanes Alkanes Alkane Systematic Nomenclature Cycloalkanes Conformations of Alkanes Conformations of Cycloalkanes Conformations of Alkylcyclohexanes
Preview You learned in the Chapter 1 that all organic molecules have carbon skeletons. These carbon skeletons show great diversity in the ways that C atoms bond to each other, and in their three-dimensional shapes. Alkanes and cycloalkanes consist entirely of carbon skeletons bonded to H atoms since they have no functional groups. As a result, they serve as a basis for understanding the structu...
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We report an experimental and simulation study of binary mixtures of oand m-nitrotoluene with decane and hexadecane. Mixtures of o-nitrotoluene with alkanes form a classical critical mixtures, but m-nitrotoluene / n – alkane mixtures show an apparent critical point, which lies in a metastable, experimentally inaccessible state, below the melting point, affecting physical and chemical properties...
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Ethanol is a hydrogen bonding liquid. When mixed in small concentrations with water or alkanes, it forms aggregate structures reminiscent of, respectively, the direct and inverse micellar aggregates found in emulsions, albeit at much smaller sizes. At higher concentrations, micro-heterogeneous mixing with segregated domains is found. We examine how different statistical methods, namely correlat...
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We investigate theoretically the binary fluid-phase behavior of mixtures in which one water-like component can have two critical points. We consider three equal-sized nonpolar solutes that differ in the strength of their dispersive interactions (a1 < a2 < a3, where a denotes the van der Waals attractive parameter). In each case, we compare the phase behavior predicted using two sets of paramete...
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ژورنال
عنوان ژورنال: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
سال: 1996
ISSN: 0021-9592,1881-1299
DOI: 10.1252/jcej.29.1054